Solid State NMR Select Publications

2012
​Theerarattananoon, K.; Xu, F.; Wilson, J.; Staggenborg, S.; McKinney, L.; Vadlani, P.; Pei, Z. J.; Wang, D. “Impact of Pelleting and Acid Pretreatment on Biomass Structure and Thermal Properties of Wheat Straw, Corn Stover, Big Bluestem, and Sorghum Stalk”, Transactions of the ASABE, 55(5), 2012, 1845-1858.

Ramanathan, A.; Maheswari, R.; Grady, B. P.; Moore, D. S.; Barich, D. H.; Subramaniam, B. “Tungsten Oxide supported cage-type mesoporous silicate: W-KIT-5, accepted to Microporous and Mesoporous Materials.

Ramanathan, A.; Maheswari, R.; Barich, D. H.; Subramaniam, B. “Niobium incorporated large pore mesoporous silicate: Synthesis and characterization”, submitted to Microporous and Mesoporous Materials.

Sun, X.; Barich, D. H.; Anthony, J. L.; “Effect of structure of ionic liquids and phosphoric acid on structure of aluminum isopropoxide”, to be submitted to Journal of Physical Chemistry A.

Dempah K. E.; Barich, D. H.; Kaushal A. M; Zong Z.; Desai S. D.; Suryanarayanan, R.; Kirsch L.; Munson E. J. “Investigating Gabapentin Polymorphism Using Solid-State NMR Spectroscopy”  AAPS Pharm. Sci. Tech. 2012, in press

2011
​Zong, Z.; Desai, S. D.; Kaushal, A. M.; Barich, D. H.; Huang, H-S.; Munson, E. J.; Suryanarayanan, R.; Kirsch, L. E. “The Stabilizing Impact of Moisture on the Solid-State Degradation of Gabapentin” AAPS Pharm. Sci. Tech. 2011, 12(3), 924–931

2009
Munson, E. J.;
Barich D. H.; Nelson, B. N. “High-Throughput systems for Magic-Angle Spinning Nuclear Magnetic Resonance.” 7,626,391, Dec. 1, 2009

1994-2006
​Zharov, I.; Havlas, Z.; Orendt, A. M.; Barich, D. H.; Grant, D. M.; Fete, M. G.; Michl, J. "CB11Me11 Boronium Ylides: Carba-closo-dodecaboranes with a Naked Boron Vertex" J. Am. Chem. Soc. 2006, 128 (18), 6089–6100

Strohmeier, M.; Barich, D. H.; Grant, D. M.; Miller, J. S.; Pugmire, R. J.; Simons, J. "Solid-State NMR Spectra and Long Intradimer Bonds in the p-[TCNE]22– Dianion" J. Phys. Chem. A 2006, 110 (25), 7962–7969.

Barich, D. H.; Gorman, E. M.; Zell, M. T.; Munson, E. J. "3-Methylglutaric Acid as a 13C Solid-State NMR Standard" Solid State NMR 2006, 30 (3-4), 125–129

Nelson, B. N.; Schieber, L. J.; Barich, D. H.; Lubach, J. W.; Offerdahl, T. J.; Lewis, D. H.; Heinrich, J. P.; Munson, E. J. "Multiple-sample Probe for Solid-State NMR Studies of Pharmaceuticals" Solid State Nucl. Magn. Reson. 2006, 29 (1–3), 204–13

Barich, D. H.; Davis, J. M.; Schieber, L. J.; Zell, M. T.; Munson, E. J. "Investigation of Solid-State NMR Line Widths of Ibuprofen in Drug Formulations" J. Pharm. Sci. 2006, 95 (7), 1586–1594

Offerdahl, T. J.; Salsbury, J. S.; Dong, Z.; Grant, D. J.; Schroeder, S. A.; Prakash, I.; Gorman, E. M.; Barich, D. H.; Munson, E. J. "Quantitation of Crystalline and Amorphous Forms of Anhydrous Neotame Using 13C CPMAS NMR Spectroscopy" J. Pharm. Sci. 2005, 94 (12), 2591–605

Harper, J. K.; Barich, D. H.; Heider, E. M.; Grant, D. M.; Franke, R. R.; Johnson, J. H.; Zhang, Y.; Lee, P. L.; Von Dreele, R. B.; Scott, B.; Williams, D.; Ansell, G. B. "A Combined Solid-State NMR and X-ray Powder Diffraction Study of a Stable Polymorph of Paclitaxel" Crystal Growth & Design 2005, 5 (5), 1737–1742

Zharov, I.; Weng, T.-C.; Orendt, A. M.; Barich, D. H.; Penner-Hahn, J.; Grant, D. M.; Havlas, Z.; Michl, J. "Metal Cation-Methyl Interactions in CB11Me12– Salts of Me3Ge+, Me3Sn+, and Me3Pb+" J. Am. Chem. Soc. 2004, 126, 12033–12046

Ma, Z.; Barich, D. H.; Solum, M. S.; Pugmire, R. J. "Solid-State 15N NMR Studies of Tobacco Leaves" J. Agric. Food Chem. 2004, 52 (2), 215–221

Barich, D. H.; Zell, M. T.; Powell, D. R.; Munson, E. J. "2,4-Dimethoxybenzoic Acid and 2,5-Dimethoxybenzoic Acid" Acta Crystallogr., Sect. C 2004, C60 (4), o261–o262.

Barich, D. H.; Zell, M. T.; Munson, E. J., "Physicochemical Properties, Formulation, and Drug Delivery". In Frontiers of Biotechnology and Pharmaceuticals, Wang, B.; Siahaan, T.; Soltero, R., Eds. John Wiley & Sons: 2004; Vol. 4

Iuliucci, R. J.; Clawson, J.; Hu, J. Z.; Solum, M. S.; Barich, D. H.; Grant, D. M.; Taylor, C. M. "Ring-chain Tautomerism in Solid-phase Erythromycin A: Evidence by Solid-State NMR" Solid State Nucl. Magn. Reson. 2003, 24 (1), 23–38

Harper, J. K.; Barich, D. H.; Hu, J. Z.; Strobel, G. A.; Grant, D. M. "Stereochemical Analysis by Solid-State NMR: Structural Predictions in Ambuic Acid" J. Org. Chem. 2003, 68 (12), 4609–4614

Harper, J. K.; Facelli, J. C.; Barich, D. H.; McGeorge, G.; Mulgrew, A. E.; Grant, D. M. "13C NMR Investigation of Solid-State Polymorphism in 10-Deacetyl Baccatin III" J. Am. Chem. Soc. 2002, 124 (35), 10589–10595

Clawson, J. S.; Strohmeier, M.; Stueber, D.; Orendt, A. M.; Barich, D. H.; Asay, B.; Hiskey, M. A.; Pugmire, R. J.; Grant, D. M. "15N Chemical Shift Tensors of b-HMX" J. Phys. Chem. A 2002, 106 (26), 6352–6357.

Barich, D. H.; Hu, J. Z.; Pugmire, R. J.; Grant, D. M. "Carbon-13 Chemical-Shift Tensors in Polycyclic Aromatic Compounds: Fluoranthene and Decacyclene" J. Phys. Chem. A 2002, 106 (27), 6477–6482

Barich, D. H.; Clawson, J. S.; Stueber, D.; Strohmeier, M.; Pugmire, R. J.; Grant, D. M. "Determination of 13C Chemical Shift Tensors in the Presence of Hydrogen Bonding and 14N Quadrupolar Coupling: p-Aminosalicylic Acid, Isoniazid, and Pyrazinamide" J. Phys. Chem. A 2002, 106 (46), 11375–11379

Harper, J. K.; Mulgrew, A. E.; Li, J. Y.; Barich, D. H.; Strobel, G. A.; Grant, D. M. "Characterization of Stereochemistry and Molecular Conformation Using Solid-State NMR Tensors" J. Am. Chem. Soc. 2001, 123 (40), 9837–9842

Barich, D. H.; Facelli, J. C.; Hu, J. Z.; Alderman, D. W.; Wang, W.; Pugmire, R. J.; Grant, D. M. "13C Chemical-shift Tensors in an Analogous Series of Heterosubstituted Polycyclic Aromatic Compounds" Magn. Reson. Chem. 2001, 39 (3), 115–121

Barich, D. H.; Nicholas, J. B.; Haw, J. F. "Gauge-Including Atomic Orbital Proton Chemical Shifts of Strong Hydrogen Bonds: The Importance of Electron Correlation" J. Phys. Chem. A 2001, 105 (19), 4708–4715

Barich, D. H.; Pugmire, R. J.; Grant, D. M.; Iuliucci, R. J. "Investigation of the Structural Conformation of Biphenyl by Solid State 13C NMR and Quantum Chemical NMR Shift Calculations" J. Phys. Chem. A 2001, 105 (28), 6780–6784

Barich, D. H.; Orendt, A. M.; Pugmire, R. J.; Grant, D. M. "Carbon-13 Chemical-Shift Tensors in Polycyclic Aromatic Compounds. 9. Biphenylene" J. Phys. Chem. A 2000, 104 (35), 8290–8295.

Haw, J. F.; Zhang, J.; Shimizu, K.; Venkatraman, T. N.; Luigi, D.-P.; Song, W.; Barich, D. H.; Nicholas, J. B. "NMR and Theoretical Study of Acidity Probes on Sulfated Zirconia Catalysts" J. Am. Chem. Soc. 2000, 122 (50), 12561–12570

Xu, T.; Barich, D. H.; Goguen, P. W.; Song, W.; Wang, Z.; Nicholas, J. B.; Haw, J. F. "Synthesis of a Benzenium Ion in a Zeolite with Use of a Catalytic Flow Reactor" J. Am. Chem. Soc. 1998, 120 (16), 4025–4026

Krawietz, T. R.; Lin, P.; Lotterhos, K. E.; Torres, P. D.; Barich, D. H.; Clearfield, A.; Haw, J. F. "Solid Phosphoric Acid Catalyst: A Multinuclear NMR and Theoretical Study" J. Am. Chem. Soc. 1998, 120 (33), 8502-8511

Goguen, P. W.; Xu, T.; Barich, D. H.; Skloss, T. W.; Song, W.; Wang, Z.; Nicholas, J. B.; Haw, J. F. "Pulse-quench Catalytic Reactor Studies Reveal a Carbon-pool Mechanism in Methanol-to-gasoline Chemistry on Zeolite HZSM-5" J. Am. Chem. Soc. 1998, 120 (11), 2650–2651

Barich, D. H.; Xu, T.; Song, W.; Wang, Z.; Deng, F.; Haw, J. F. "N-Alkylnitrilium Cations in Zeolites: A Study Using Theoretical Chemistry and in Situ NMR with the Pulse-Quench Reactor" J. Phys. Chem. B 1998, 102 (37), 7163–7168.

Barich, D. H.; Xu, T.; Zhang, J.; Haw, J. F. "Modeling of Benzene Adsorption in Metal-exchanged Zeolites by Calculation of 7Li Chemical Shifts" Angewandte Chemie, International Edition 1998, 37 (18), 2530–2531.

Barich, D. H.; Nicholas, J. B.; Xu, T.; Haw, J. F. "Theoretical and Experimental Study of the 13C Chemical Shift Tensors of Acetone Complexed with Bronsted and Lewis acids" J. Am. Chem. Soc. 1998, 120 (47), 12342–12350

Xu, T.; Barich, D. H.; Torres, P. D.; Haw, J. F. "Benzenium Ion Chemistry on Solid Metal Halide Superacids: In Situ 13C NMR Experiments and Theoretical Calculations" J. Am. Chem. Soc. 1997, 119 (2), 406–414

Xu, T.; Barich, D. H.; Torres, P. D.; Nicholas, J. B.; Haw, J. F. "Carbon-13 Chemical Shift Tensors for Acylium Ions: A Combined Solid State NMR and Ab Initio Molecular Orbital Study" J. Am. Chem. Soc. 1997, 119 (2), 396–405

Prasad, S.; Barich, D. H.; Haw, J. F. "Probing Acid Sites in MAPO-36 by Solid State NMR" Catal. Lett. 1996, 39 (3,4), 141–146

Nicholas, J. B.; Xu, T.; Barich, D. H.; Torres, P. D.; Haw, J. F. "13C Chemical Shift Tensor of the Isopropyl Cation" J. Am. Chem. Soc. 1996, 118 (17), 4202–3.

Krawietz, T. R.; Barich, D. H.; Beck, L. W.; Howard, T.; Xu, T.; Haw, J. F. "NMR Observation of a Zinc Carbonyl in Zeolite ZnY" J. Am. Chem. Soc. 1995, 117 (41), 10407–8.

Neue, G.; Dybowski, C.; Smith, M. L.; Barich, D. H. "Fitting of Low-intensity Wide-line Spectra Dominated by Chemical Shift Anisotropy" Solid State NMR 1994, 3 (3), 115–19


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EVENTS
Ability to set up 24 NMR experiments at one time and eliminate periodic user intervention
Screen up to 100,000 compounds in two days for endpoint assays
Next-generation genome sequencing
Near-infrared and bioluminescence imaging instrumentation to track gene of interest and/or tumor growth
Expertise in the design and stability of various pharmaceutical dosage forms
More than 40 computational chemistry software programs and databases
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